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示波极谱法连续测定稀土氧化物中铕和镱
引用本文:陈达仁,林明德. 示波极谱法连续测定稀土氧化物中铕和镱[J]. 分析测试学报, 1988, 0(4)
作者姓名:陈达仁  林明德
作者单位:广东省地质测试研究中心(陈达仁),广州市环境监测中心站(林明德)
摘    要:研究表明,除铕及镱外,用极谱法难以测定其它稀土元素。Laitinen等曾以0.1M氯化铵为支持电解质,在pH5~6下以经典极谱法测铕和镱,其半波电位分别为-0.671和-1.415伏。其后亦有人以氯化钙、氯化钾作底液,用经典极谱法测铕和镱。本文介绍以示波极


The Consecutive Determination of Europium and Ytterbium in Rare Earths by Oscilloscopic Polarography
Chen Daren,Lin Mingde Geological Analysis Testing Research Centre of Guangdong Province Guangzhou Enviroment Monitering Centre. The Consecutive Determination of Europium and Ytterbium in Rare Earths by Oscilloscopic Polarography[J]. Journal of Instrumental Analysis, 1988, 0(4)
Authors:Chen Daren  Lin Mingde Geological Analysis Testing Research Centre of Guangdong Province Guangzhou Enviroment Monitering Centre
Affiliation:Chen Daren;Lin Mingde Geological Analysis Testing Research Centre of Guangdong Province Guangzhou Enviroment Monitering Centre
Abstract:For selection of appropriate supporting electrolyte in oscilloscopic polarographic determi-nation of europium and ytterbium, calcium chloride, potassium chloride and ammoium chloridewere compared, It was found that ammonium chloride solution is a suitable supporting electro-lyte for determination of europium and ytterbium and that the results obtained agree withthe requirement of ore analysis.
Keywords:Rare earth  europium  ytterbium  oscilloscopic polarographic
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