| 氟化钾催化含氢烷氧基硅烷的歧化反应 |
| |
| 引用本文： | 张增佑 尚坚. 氟化钾催化含氢烷氧基硅烷的歧化反应[J]. 高等学校化学学报, 1995, 16(11): 1749-1751 |
| |
| 作者姓名： | 张增佑 尚坚 |
| |
| 作者单位： | 南开大学元素有机化学研究所 |
| |
| 摘 要： | 氟化钾催化含氢烷氧基硅烷的歧化反应张增佑，尚坚，周秀中（南开大学元素有机化学研究所化学系，天津，５０００７１）关键词歧化反应，氟化物，催化，烷氧基硅烷早在７０年代初期Ａｋｌｉｒｅｍ［１］就报道了氟化物可催化硅氢化物醇解。关于氟化物活化Ｓｉ—Ｈ键的实质...
|
| 关 键 词： | 歧化反应 催化 烷氧基硅烷 氟化钾 |
The Disproportionation of Hydroalkoxysilanes Catalyzed by KF |
| |
| ZHANG Zeng-You,SHANG Jian, Zhou Xiou-Zhong. The Disproportionation of Hydroalkoxysilanes Catalyzed by KF[J]. Chemical Research In Chinese Universities, 1995, 16(11): 1749-1751 |
| |
| Authors: | ZHANG Zeng-You SHANG Jian Zhou Xiou-Zhong |
| |
| Abstract: | The disproportionation of(C_2H_5O)_3SiH and CH_3SiH(OC2Hs)2 using DMF or THF as the solvents in the presence of KF(and 18-crown-6)was studied and the effects of catalyst system,temperature and solvent on the disproportionation were discussed. The results showed that KF/18-crown-6 is a good catalytic system for the disproportionation of hydroalkoxysilones, the solvent and temperature affect obviously the reaction. |
| |
| Keywords: | Disproportionation Fluorides Catalysis Alkoxysilanes |
| 本文献已被 CNKI 维普 等数据库收录！ |
