Direct and outer-sphere coordination of the magnesium ions in the crystal structures of complexes with 2-furancarboxylic acid (I) and 3-furancarboxylic acid (II) |
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Authors: | Beata Paluchowska Jan K. Maurin Janusz Leciejewicz |
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Affiliation: | (1) Institute of Atomic Energy, 05-400 Świerk-Otwock Warsaw, Poland;(2) Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195 Warsaw, Poland |
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Abstract: | (I) Mg2C20H24O18 monoclinic,PT,a=10.760(2) Å,b=11.052(2) Å,c=12.822(3) Å, α=105.31(3)o, β=98.18(3)o, γ=91.59(3)o,Z=2. (II) MgC10H14O10, monoclinic,C2/c,a=30.817(6)Å,b=10.499(2)Å,c=9.000(2)Å, β=91.31(3)o,Z=8. Magnesium in complexes with furoic acids reveals two ways of coordination: direct, when furoic anions are bonded to Mg2+ in an ionic fashion and outer-sphere, when cations bind water in the first coordination sphere and furancarboxylic ligands are hydrogen bonded to the water molecules. This results in the formation of three bridging systems: ?Mg?Ocarboxyl?C?Ocarboxyl?Mg?, ?Mg?Owater ?Ocarboxyl?C?Ocarboxyl?C?Ocarboxyl?Mg?, and ?Mg?Owater?Ocarboxyl?C?Ocarboxyl?Owater?Mg?. Magnesium 2-furancarboxylate (I) is dimeric, while magnesium 3-furancarboxylate (II) exhibits a polymeric structure. |
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Keywords: | 3-Furancarboxylic acid 2-furancarboxylic acid magnesium compounds X-ray structure analysis |
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