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单晶YSZ的Xe+离子辐照效应研究
引用本文:向霞,祖小涛,张传飞,王治国,朱莎,曾光廷,霍永忠,王鲁闽.单晶YSZ的Xe+离子辐照效应研究[J].强激光与粒子束,2003,15(4):405-408.
作者姓名:向霞  祖小涛  张传飞  王治国  朱莎  曾光廷  霍永忠  王鲁闽
作者单位:1. 电子科技大学 应用物理系, 四川 成都 610054;2. 中国工程物理研究院 核物理与化学研究所, 四川 绵阳 621900;3. Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, MI48109
基金项目:国家自然科学基金资助课题(10175042);教育部留学回国人员科研启动基金资助课题
摘    要: 200keV Xe+离子辐照使单晶YSZ由无色透明变成紫色透明,结果表明,能量为200keV,注量为1×1017cm-22的Xe+离子辐照YSZ单晶产生的损伤高达350dpa,在损伤区产生高密度的缺陷,但仍然没有发生非晶化转变。吸收光谱测试结果表明,产生吸收带的注量阈值大约为1016cm-2。注量为1×1016cm-2和1×1017cm-2的样品,吸收带峰值分别位于522nm和497nm。光吸收带可能与Zr阳离子最近邻的氧空位捕获电子形成的F型色心和Y阳离子近邻的氧离子捕获空穴形成的V型色心有关。

关 键 词:单晶YSZ  重离子辐照效应  剖面TEM  吸收光谱
文章编号:1001-4322(2003)04-0405-04
收稿时间:2002/7/18
修稿时间:2002年7月18日

Study of Xe+-irradiation effect on yttria-stabilized zirconia single crystals
xiang xia,zu xiao tao,zhang chuan fei,wang zhi guo,zhu sha,zeng guang ting,huo yong zhong,wang lu min.Study of Xe+-irradiation effect on yttria-stabilized zirconia single crystals[J].High Power Laser and Particle Beams,2003,15(4):405-408.
Authors:xiang xia  zu xiao tao  zhang chuan fei  wang zhi guo  zhu sha  zeng guang ting  huo yong zhong  wang lu min
Institution:1. Department of Applied Physics, University of Electronic Science and Technology of China, Chengdu 610054, China;2. Institute of Nuclear Physics and Chemistry, CAEP, Mianyang 621900, China;3. Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, MI48109, USA
Abstract:A transparent yttria stabilized zirconia (YSZ) single crystal becomes purple after 200keV Xe+ irradiation. Calculation of TRIM 96 shows that 200keV Xe+ ions cause peak displacement levels of ~350dpa (displacement per atom) at the depth of 30nm in a YSZ single crystal at a dose of 1×1017cm-2, and cross sectional TEM images and diffraction pattern show that there is no amorphization. Optical absorption measurements show that a broad absorption band appears at a dose of 1×1016cm-2. For the 1×1016cm-2 and 1×1017cm-2Xe+ irradiated crystals, the absorption bands are centered at 522nm and 497nm, respectively. The bands are assigned to electrons trapped at oxygen vacancies nearest to Zr cations (F type centers) and to oxygen ions with trap holes adjacent to yttria cations (V type centers).
Keywords:YSZ single crystal  Heavy ion irradiation  Cross-sectional TEM  Optical absorption spectrum
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