Hollow porphyrin prisms: modular formation of permanent, torsionally rigid nanostructures via templated olefin metathesis |
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| Authors: | Youm Kyoung-Tae Nguyen SonBinh T Hupp Joseph T |
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| Institution: | Department of Chemistry, Northwestern University, Evanston, IL 60208-3113, USA. |
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| Abstract: | Hollow, hexa-porphyrin prisms of two sizes were template-assembled and covalently locked, via cross-olefin metathesis, into permanent, torsionally rigid structures whose active sites (metal sites) can be both accessed and altered in a facile manner. |
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