Stereoselective multimodal transformations of planar chiral 9-membered diallylic amides |
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| Authors: | Tomooka Katsuhiko Suzuki Masaki Shimada Maki Ni Runyan Uehara Kazuhiro |
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| Institution: | Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga-shi, Fukuoka 816-8580, Japan. ktomooka@cm.kyushu-u.ac.jp |
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| Abstract: | Intermolecular reactions of planar chiral 9-membered diallylic amides provide a variety of bicyclic compounds with central chiralities in a stereospecific fashion with high group selectivity. Lewis-acid-promoted intramolecular reactions of the obtained bicyclic compounds provide transannular products in a stereospecific fashion. Furthermore, a direct transannular reaction of diallylic amide involving sequential intermolecular-intramolecular reactions has been developed. |
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