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低聚醚磺酸锂/梳形聚醚复合物的单离子导电性
引用本文:郑云贵,万国祥.低聚醚磺酸锂/梳形聚醚复合物的单离子导电性[J].高分子学报,1995(3).
作者姓名:郑云贵  万国祥
作者单位:中国科学院成都有机化学研究所
基金项目:国家“863”计划资助
摘    要:低聚醚磺酸锂/梳形聚醚复合物的单离子导电性郑云贵,万国祥(中国科学院成都有机化学研究所成都610041)关键词低聚醚磺酸锂,单离子导体,阳离子迁移数聚合物阳离子导体一般采用单体盐与能促进离子迁移的单体通过共聚或将其均聚物共混的方式制备’‘-‘’.由于...

关 键 词:低聚醚磺酸锂,单离子导体,阳离子迁移数

SINGLE-ION CONDUCTION OF LITHIUM OLIGOETHER SULFONATE/COMBLIKE POLYETHER COMPLEX
ZHENG Yungui, WAN Guoxiang.SINGLE-ION CONDUCTION OF LITHIUM OLIGOETHER SULFONATE/COMBLIKE POLYETHER COMPLEX[J].Acta Polymerica Sinica,1995(3).
Authors:ZHENG Yungui  WAN Guoxiang
Abstract:A complex ionic conductor was prepared by solution complexation of lithium methoxy oligo (oxyethylene) sulfonate (SOL8, where & is the repeating unit of oxyethylene) with comblike copolyether poly methoxy oligo (oxyethylene)methacrylate-co-acrylamide] P(MEO16-AM)]. The composition dependences of glass transition temperature,crystallinity as well as conducti-vity of the complex were investigated. DC polarization showed that the complex shows a stable polarization characteristic. Polarization reversing method confirmed that the complex has a cationic transference number of 0.99.
Keywords:Lithium oligoether sulfonate  Single-ion conductor  Cationic transference number  
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