Camel's back structure of the conduction band in GaP

A simple k · p theory based on Si and the ionic X gap is applied to the conduction band of GaP. It is found that recent evidence may indicate a location of the absolute minima away from the zone boundary. In the directions parallel to 〈100〉, the band structure is highly nonparabolic for carrier energies in the range 1–50 meV.