A simple method for the determination of the partitioning of nitroxide probes in microheterogeneous media |
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Authors: | Carolina Aliaga Paulina Torres Fernanda Silva |
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Affiliation: | 1. Facultad de Química y Biología, Universidad de Santiago de Chile, , Santiago de Chile, Chile;2. Centro para el Desarrollo de la Nanociencia y la Nanotecnología (CEDENNA), , Chile |
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Abstract: | The use of the ESR g‐factor of spin labels for the easy and clean assessment of their partitioning in microheterogeneous media is described. The method constitutes a valuable alternative in those cases where the classical Benesi–Hildebrand treatment, based on UV–visible measurements, is difficult or not feasible. Copyright © 2012 John Wiley & Sons, Ltd. |
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Keywords: | NMR g‐factor micelle partition constant nitroxide probe |
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