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暴露{001}面TiO2纳米片分等级花状结构的制备及其光催化活性
引用本文:向全军,余家国.暴露{001}面TiO2纳米片分等级花状结构的制备及其光催化活性[J].催化学报,2011,32(4):525-531.
作者姓名:向全军  余家国
作者单位:武汉理工大学材料复合新技术国家重点实验室;
基金项目:supported by the National Natural Science Foundation of China(50625208,20773097,and 20877061); the National Basic Research Program of China(973Program,2007CB613302and2009CB939704); Fundamental Research Funds for the Central Universities(2010-YB-01)~~
摘    要:以钛酸盐纳米管为前驱体,在HF-H2O-C2H5OH的混合溶液中,采用一种简单的醇热方法合成了具有87%暴露{001}面的TiO2纳米片自组装形成的分等级花状TiO2超结构.运用X射线衍射、扫描电镜、透射电镜和N2吸附-脱附等方法对样品进行了表征,并在紫外光照射下于空气和溶液中分别考察了其光催化降解丙酮和甲基橙反应活性...

关 键 词:二氧化钛  纳米片  {001}晶面  分等级花状二氧化钛超结构  光催化活性  丙酮  甲基橙

Photocatalytic Activity of Hierarchical Flower-Like TiO_2 Superstructures with Dominant {001} Facets
XIANG Quanjun,YU Jiaguo.Photocatalytic Activity of Hierarchical Flower-Like TiO_2 Superstructures with Dominant {001} Facets[J].Chinese Journal of Catalysis,2011,32(4):525-531.
Authors:XIANG Quanjun  YU Jiaguo
Institution:XIANG Quanjun,YU Jiaguo State Key Laboratory of Advanced Technology for Material Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,Hubei,China
Abstract:The fabrication of well defined hierarchical structures of anatase TiO2 with a high percentage of reactive facets is of great importance and challenging.Hierarchically flower-like TiO2 superstructures (HFTS) self-assembled from anatase TiO2 nanosheets with exposed {001} facets (up to 87%) were synthesized by a simple alcohothermal strategy in a HF-H2O-C2H5OH mixed solution using titanate nanotubes as precursor.The samples were characterized by X-ray diffraction,scanning electron microscopy,transmission elec...
Keywords:titanium dioxide  {001} facet  hierarchical flower-like titanium dioxide superstructure  photocatalytic activity  acetone  methyl orange  
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