| 介孔硅担载磷钨杂多酸催化剂的制备及其对环戊烯氧化反应的催化性能 |
| |
| 引用本文： | 袁程远,陈静.介孔硅担载磷钨杂多酸催化剂的制备及其对环戊烯氧化反应的催化性能[J].催化学报,2011,32(7):1191-1198. |
| |
| 作者姓名： | 袁程远 陈静 |
| |
| 作者单位： | 1. 中国科学院兰州化学物理研究所羰基合成和选择氧化国家重点实验室,甘肃兰州730000;中国科学院研究生院,北京100049
2. 中国科学院兰州化学物理研究所羰基合成和选择氧化国家重点实验室,甘肃兰州,730000 |
| |
| 基金项目： | 国家杰出青年科学基金(20625308)~~ |
| |
| 摘 要： | 采用离子交换法将Keggin型12-磷钨杂多酸负载到表面胺基化的介孔SBA-15分子筛上,并利用X射线衍射、N2吸附-脱附、傅里叶变换红外光谱、X射线光电子能谱和热重分析等手段对催化剂进行了表征.结果表明,所制备催化剂具有SBA-15分子筛的有序六方孔道结构,负载后的磷钨杂多酸的Keggin结构未遭到破坏,所制备催化剂...
|
| 关 键 词： | 杂多酸 环戊烯 戊二醛 选择性氧化 SBA-15 |
Preparation of Heterogeneous Mesoporous Silica-Supported 12-Tungstophosphoric Acid Catalyst and Its Catalytic Performance for Cyclopentene Oxidation |
| |
| YUAN Chengyuan,CHEN Jing.Preparation of Heterogeneous Mesoporous Silica-Supported 12-Tungstophosphoric Acid Catalyst and Its Catalytic Performance for Cyclopentene Oxidation[J].Chinese Journal of Catalysis,2011,32(7):1191-1198. |
| |
| Authors: | YUAN Chengyuan CHEN Jing |
| |
| Institution: | YUAN Chengyuan1,2,CHEN Jing1,1State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,Gansu,China 2Graduate University of Chinese Academy of Sciences,Beijing 100049,China |
| |
| Abstract: | Keggin-structured 12-tungstophosphoric acids were immobilized onto the surface of amine-modified mesoporous sieve SBA-15 as onium salts. All the catalyst materials were characterized by X-ray diffraction,N2 physisorption,Fourier transform infrared spectroscopy,thermal gravimetric analysis,and X-ray photoelectron spectroscopy for their structural integrity and physicochemical properties. Characteri-zation of the catalysts confirmed an ordered hexagonal mesostructure for SBA-15 and that the Keggin structure o... |
| |
| Keywords: | heteropolyacid cyclopentene glutaraldehyde selective oxidation SBA-15 |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
