| [Cu(2,2'-bpy)Cl2]和[Cu(1,10-phen)C12]在多金属氧酸盐上的多相化:选择性氧化四氢化萘的新催化剂 |
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| 作者姓名： | M.BOLTZ A.BLANC G.LAUGEL P.PALE B.LOUIS |
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| 作者单位： | Laboratoire de Synthèse et RéactivitéOrganiques;Institut de Chimie;UMR 7177 CNRS;Universitéde Strasbourg; |
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| 摘 要： |
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| 关 键 词： | 新催化剂 多相化 选择性氧化 四氢化萘 多金属氧酸盐 |
Heterogenization of [Cu(2,2'-bpy)Cl2] and [Cu(l,10-phen)Cl2] on Polyoxometalates: New Catalysts for the Selective Oxidation of Tetralin |
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| M.BOLTZ,A.BLANC,G.LAUGEL,P.PALE,B.LOUIS.Heterogenization of [Cu(2,2''-bpy)Cl2] and [Cu(l,10-phen)Cl2] on Polyoxometalates: New Catalysts for the Selective Oxidation of Tetralin[J].Chinese Journal of Catalysis,2011,32(5). |
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| Authors: | M BOLTZ A BLANC G LAUGEL P PALE B LOUIS |
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| Institution: | M.BOLTZ,A.BLANC,G.LAUGEL,P.PALE,B.LOUIS* Laboratoire de Synthèse et RéactivitéOrganiques,Institut de Chimie,UMR 7177 CNRS,Universitéde Strasbourg,4 rue Blaise Pascal,67000,Strasbourg Cedex,France |
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| Abstract: | Mononuclear Cu(II)bipyridine(1)and phenantroline complexes(2)were synthesized and immobilized by different procedures on H3PW12O40 polyoxometalate(POM).Characterization by XRD and SEM-EDX were performed to assess the preservation of the Keggin structure and stoichiometry of the complex.The immobilized complexes were tested as heterogeneous catalysts for the partial oxidation of tetralin(1,2,3,4-tetrahydronaphthalene)using hydrogen peroxide as oxidant in acetonitrile/water as solvent.Cu(2,2'-bpy)Cl]H2PW12O... |
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| Keywords: | tetralin partial oxidation Cu(II)complexes 2 2'-bipyridine 1 10-phenantroline hydrogen peroxide polyoxometalate |
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