| 以羰基磷氧化物为配体的铜催化的C-S偶联反应 |
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| 引用本文： | 王浩龙,万伯顺.以羰基磷氧化物为配体的铜催化的C-S偶联反应[J].催化学报,2011,32(7):1129-1132. |
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| 作者姓名： | 王浩龙 万伯顺 |
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| 作者单位： | 中国科学院大连化学物理研究所,辽宁大连,116023 |
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| 摘 要： | 以邻溴苯甲醛为原料合成了一系列的羰基磷氧化物,用作铜催化的C-S偶联反应的新配体.在较温和的反应条件下可成功催化碘代芳烃或溴代芳烃与硫醇的偶联反应,收率最高达99%.
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| 关 键 词： | 铜 羰基磷氧化物 碳硫成键反应 偶联反应 碘代芳烃 硫醇 |
Cu-Catalyzed Coupling of Aryl Iodides with Thiols Using Carbonyl-Phosphine Oxide Ligands |
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| WANG Haolong,WAN Boshun.Cu-Catalyzed Coupling of Aryl Iodides with Thiols Using Carbonyl-Phosphine Oxide Ligands[J].Chinese Journal of Catalysis,2011,32(7):1129-1132. |
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| Authors: | WANG Haolong WAN Boshun |
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| Institution: | WANG Haolong,WAN Boshun Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,Liaoning,China |
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| Abstract: | A series of carbonyl-phosphine oxide ligands were synthesized from 2-bromophenylaldehyde and used in Cu-catalyzed C–S cou-pling reactions. Aryl iodide and aryl bromide reacted with thiols efficiently upon catalysis under mild reaction conditions and a yield of up to 99% was obtained. |
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| Keywords: | Cu carbonyl-phosphine oxide carbon-sulfur bond formation cross-coupling reaction iodide aryl thiol |
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