The one‐pot direct synthesis of 2‐aminobenzothiazoles from phenyl isothiocyanate and amines using a new reagent of 1‐butyl‐3‐methylimidazolium tribromide (Bmim]Br3) in ionic liquid 1‐butyl‐3‐methylimidazolium tetraflouoroborate (Bmim]BF4) is described.