Four-color hole burning spectra of phenol/ammonia 1:3 and 1:4 clusters |
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Authors: | Ishiuchi Shun-Ichi Daigoku Kota Hashimoto Kenro Fujii Masaaki |
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Affiliation: | Chemical Resources Laboratory, Tokyo Institute of Technology/PRESTO-JST, Nagatsuta-cho, Midoriku, Yokohama 226-8503, Japan. |
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Abstract: | The hole burning spectra of phenol/ammonia (1:3 and 1:4) clusters were measured by a newly developed four-color (UV-near-IR-UV-UV) hole burning spectroscopy, which is a kind of population labeling spectroscopy. From the hole burning spectra, it was found that single species is observed in an n = 3 cluster, while three isomers are observed simultaneously for n = 4. A possibility was suggested that the reaction efficiency of the hydrogen transfer from the electronically excited phenol/ammonia clusters, which was measured by a comparison with the action spectra of the corresponding cluster, depends on the initial vibronic levels. |
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