Stereoselective synthesis of (Z)-β-fluoro-α,β-unsaturated esters from (Z)-2-fluoro-1-alkenyliodonium salts |
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| Authors: | Masanori Yoshida |
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| Affiliation: | Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan |
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| Abstract: | (Z)-β-Fluoro-α,β-unsaturated esters were stereoselectively synthesized from (Z)-2-fluoro-1-alkenyliodonium salts by the Pd-catalyzed methoxycarbonylation reaction. The reaction proceeded at room temperature and various functional groups on the substrate can tolerate the reaction conditions. |
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| Keywords: | (Z)-2-fluoro-1-alkenyliodonium salts (Z)-β-fluoro-α,β-unsaturated esters Methoxycarbonylation reaction Pd catalyst |
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