Synthesis of perfluorinated functionalized, branched ethers |
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Authors: | Kyle W Felling Cameron R Youngstrom |
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Institution: | a Department of Chemistry and Chemical Engineering, South Dakota School of Mines and Technology, 501 East St. Joseph Street, Rapid City, SD 57701-3995, USA b Department of Chemistry and Biochemistry, College of Natural Sciences, Mail Code A5300, The University of Texas at Austin, Austin, TX 78712-1167, USA |
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Abstract: | We wish to report synthesis of perfluorinated functionalized, branched ethers from their hydrocarbon analogues by direct fluorination. Yields up to 90%, with high purities, have been obtained at ambient temperature and pressure. This technique will likely develop into a new general method for producing perfluorinated, hyperbranched and dendritic polymers. |
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Keywords: | Direct fluorination Perfluorinated ethers Hyperbranched polymers Dendrimers |
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