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Synthesis of perfluorinated functionalized, branched ethers
Authors:Kyle W Felling  Cameron R Youngstrom
Institution:a Department of Chemistry and Chemical Engineering, South Dakota School of Mines and Technology, 501 East St. Joseph Street, Rapid City, SD 57701-3995, USA
b Department of Chemistry and Biochemistry, College of Natural Sciences, Mail Code A5300, The University of Texas at Austin, Austin, TX 78712-1167, USA
Abstract:We wish to report synthesis of perfluorinated functionalized, branched ethers from their hydrocarbon analogues by direct fluorination. Yields up to 90%, with high purities, have been obtained at ambient temperature and pressure. This technique will likely develop into a new general method for producing perfluorinated, hyperbranched and dendritic polymers.
Keywords:Direct fluorination  Perfluorinated ethers  Hyperbranched polymers  Dendrimers
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