Highly stereoselective oxidative esterification of aldehydes with beta-dicarbonyl compounds |
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Authors: | Yoo Woo-Jin Li Chao-Jun |
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Affiliation: | Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 2K6, Canada. |
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Abstract: | Copper-catalyzed oxidative esterification of aldehydes with beta-dicarbonyl compounds was developed using tert-butyl hydroperoxide as an oxidant. In general, the enol esters were synthesized in good yields (up to 87%) and high stereoselectivity under the optimized reaction conditions. |
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