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Highly stereoselective oxidative esterification of aldehydes with beta-dicarbonyl compounds
Authors:Yoo Woo-Jin  Li Chao-Jun
Institution:Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 2K6, Canada.
Abstract:Copper-catalyzed oxidative esterification of aldehydes with beta-dicarbonyl compounds was developed using tert-butyl hydroperoxide as an oxidant. In general, the enol esters were synthesized in good yields (up to 87%) and high stereoselectivity under the optimized reaction conditions.
Keywords:
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