A Novel Hydrogen-bonded Three-dimensional Network Complex Containing Nickel |
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| Authors: | WANG Li LI Juan WANG En-bo |
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| Institution: | Institute of Polyoxometalate Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P.R. China |
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| Abstract: | A novel complex, (H3O)2Ni(2,6-pydc)2]·2H2O was synthesized in an aqueous solution and characterized by means of single-crystal X-ray diffraction, elemental analyses and IR spectra. The X-ray structural analysis revealed that the novel compound forms three-dimensional(3D) networks by both π-π stacking and hydrogen-bonding interactions. The crystal data for the complex are a = 13. 853 (3) nm, b= 9. 6892 (19) nm,c=13.732(3) nm, α=90. 00°, β=115.52(3)°, γ=90.00°, Z=3, R1=0.0786, wR2=0.1522. |
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| Keywords: | Stacking Hydrogen-bonding interaction Three-dimensional(3D) network 2 6-Pyridinedicarboxylic acid |
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