Electrochemical Studies of Eight New Divalent Transition Metal Benzenesulphonate Ternary Complexes with 1,10-Phenanthroline |
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| Authors: | LU Yao GUO Li-ping MA Jian-fang YANG Jin WU Dongmei |
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| Institution: | 1. Faculty of Chemistry, Northeast Normal University, Changchun 130024, China;
2. College of Chemistry & Pharmocology, Jiamusi University, Jiamusi 154002, China |
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| Abstract: | The electrochemical properties of eight new divalent transition metal benzenesulphonate complexes with 1,10-phenanthroline in different solvents and supporting electrolytes were investigated by means of cyclic voltammetry(CV). Based on the CV data the influences of various coordination modes on the electrochemical behavior of the complexes were discussed. The diffusion coefficient Dc and rate constant ks of those complexes in DMF systems were estimated according to CV and the results show that these processes were all quasi-reversible. |
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| Keywords: | Benzenesulphonate 1 10-Phenanthroline Transition metal complex Cyclic voltammetry |
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