Synthesis of the (dialkylamino)borate, [Ph(2)B(CH(2)NMe(2))(2)](-), affords access to N-chelated rhodium(I) zwitterions |
| |
| Authors: | Betley Theodore A Peters Jonas C |
| |
| Institution: | Division of Chemistry and Chemical Engineering, Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA. |
| |
| Abstract: | This paper reports the synthesis of the first bis(amino)borate ligand, Ph(2)B(CH(2)NMe(2))(2)](-), an anionic equivalent of tertiary diamines. Anionic Ph(2)B(CH(2)NMe(2))(2)] is an excellent bidentate ligand auxiliary and is used to prepare a series of N-chelated, zwitterionic rhodium(I) complexes. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
