| 过渡金属原子簇中的协同效应 |
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| 引用本文： | 刘汉钦.过渡金属原子簇中的协同效应[J].结构化学,1993,12(6):409-416. |
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| 作者姓名： | 刘汉钦 |
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| 作者单位： | 结构化学国家重点实验室 中国科学院福建物质结构研究所 |
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| 摘 要： | 以铁硫、铁钼硫簇合物为例对过渡金属簇合物中的协同效应进行了讨论。利用结构谱学数据,从簇骼转化、电子加入对簇骼的影响,端基、桥基、非邻近基团的作用等几个方面讨论了铁硫、铁钼硫簇合物中各种基团之间的相互作用。
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| 关 键 词： | 金属原子簇 铁硫簇合物 铁钼硫簇合物 协同效应 |
The Synergism in Transition Metal Cluster Compounds |
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| Liu Han-QinState Key Laboratory of Structural Chemistry,and Fujian Institute of Research on the Structure of Matter,Chineses Academy of Sciences,Fuzhou.The Synergism in Transition Metal Cluster Compounds[J].Chinese Journal of Structural Chemistry,1993,12(6):409-416. |
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| Authors: | Liu Han-QinState Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter Chineses Academy of Sciences Fuzhou |
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| Institution: | Liu Han-QinState Key Laboratory of Structural Chemistry,and Fujian Institute of Research on the Structure of Matter,Chineses Academy of Sciences,Fuzhou,350002 |
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| Abstract: | This is a review article to summarize the synergism in transition metal clusters on the basis of the research results of iron-sulfur,iron-molybdennum-sulfur clusters.With structural and spectroscopic data,we have discussed the interactions among various groups of iron-sulfur,iron-molybdenum-sulfur cluster compounds in many aspects,such as transformation of cluster cores,the effect of electron addition to cluster cores,and the roles of terminal,bridging,and non-adjacent groups. |
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| Keywords: | Metal clusters iron-sulfur cluster compound iron-molybdenum-sulfur cluster compound synergism |
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