Catalytic properties of palladium complexes with silica-anchored phosphine ligands in vinyl exchange reaction |
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| Authors: | S. I. Chistyakov V. A. Semikolenov V. A. Likholobov Yu. I. Yermakov |
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| Affiliation: | (1) Institute of Catalysis, Novosibirsk, USSR |
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| Abstract: | Catalytic properties of Pd complexes with phosphine ligands anchored to silica have been studied. The valence state of Pd and the acidity of the alcohol were found to influence the rate of vinyl exhange. A possible reaction mechanism is proposed.
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