High-spin M2+ carboxylate triangles from the microwave |
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| Authors: | Milios Constantinos J Prescimone Alessandro Sanchez-Benitez J Parsons Simon Murrie Mark Brechin Euan K |
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| Institution: | School of Chemistry and Centre for Science at Extreme Conditions, University of Edinburgh, West Mains Road, Edinburgh EH9 3JJ, U.K. |
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| Abstract: | The reaction of M(O2CMe)2.4H2O (M = Ni, Co) with NaN3 in pyridine/MeOH under microwave irradiation and controlled pressure/temperature leads to the formation of the trimetallic species M3(N3)3(O2CMe)3(py)5] (M = Ni, 1; Co, 2) in 4 min and in high yields. Both complexes display dominant ferromagnetic interactions and high-spin ground states. |
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