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Alkylation and acylation of C-phosphorylated acetamidines involving CH-acidic methylene group |
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| Authors: | V. E. Shishkin E. V. Mednikov M. A. Shevchenko O. V. Anishchenko Yu. V. Popov |
| Affiliation: | (1) Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, 02094, Ukraine;(2) National Agricultural University of Ukraine, Kiev, 03041, Ukraine;(3) Research and Development Center for Chemistry and Biology, Kiev T. Shevchenko National University, Kiev, 01033, Ukraine |
| Abstract: | Reactions of sodium derivatives of C-phosphorylated acetamidines containing CH-acidic methylene group with alkyl and acyl halides were studied. The interaction occurs selectively to form the products of alkylation and acylation of methylene group, respectively. A convenient method for the synthesis of C-alkylated and C-acylated derivatives of C-phosphorylated acetamidines was developed. |
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