Bidentate ligand-catalyzed enantioselective addition of RZnX to benzaldehyde |
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| Authors: | R.S. JagtapN.N. Joshi |
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| Affiliation: | Division of Organic Chemistry, National Chemical Laboratory, Pune 411 008, India |
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| Abstract: | Enantioselective addition of RZnX (R = alkyl, X = Cl, OAc) was studied using chiral chelating agents, particularly metal-alkoxides. Moderate enantioselectivity was achieved in the presence of magnesium-TADDOLate using RZnOAcMg(OAc)Br as the alkylating agent. |
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| Keywords: | Asymmetric synthesis Organozinc Chelating ligands 1,2-Addition |
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