Thermal and light induced polymorphism in iron(II) spin crossover compounds |
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| Authors: | Thompson Amber L Goeta Andres E Real Jose A Galet Ana Carmen Munoz M |
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| Institution: | Department of Chemistry, University of Durham, South Road, Durham, UKDH1 3LE. |
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| Abstract: | The spin crossover complexes FeH(2)B(pz)(2)](2)L](H(2)B(pz)(2)](-)= dihydrobis(pyrazolyl)borate, L = 2,2prime or minute]-bipyridine (1), bipy and 1,10-phenanthroline, phen (2)) undergo both thermal and light induced spin crossover, but the structure of the low spin and light induced high spin states for are different from that of the thermally induced high spin state and from those of. |
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