Spectrophotometric determination of iron(II) after separation by adsorption of its complex with 3-(4-phenyl-2-pyridyl)-5,6-diphenyl-1,2,4-triazine and tetraphenylborate on microcrystalline naphthalene |
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Authors: | Nagahiro T Uesugi K Mehra M C Satake M |
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Institution: | Himeji Institute of Technology, 2167, Shosha, Himeji-shi, Hyōgo, Japan. |
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Abstract: | Trace iron(II) is determined spectrophotometrically after adsorption of its ternary complex with 3-(4-phenyl-2-pyridyl)-5,6-diphenyl-1,2,4-triazine and tetraphenylborate on microcrystalline naphthalene at pH 5.1–7.4. The absorption maximum is at 567 nm; the molar absorptivity is 2.9 × 104lmole−1cm−1. |
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