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Convergent-beam electron diffraction of CaZr4O9, a complex zirconia alloy phase
Authors:Miao Lin and J R Sellar
Institution:

Department of Materials Engineering, Monash University, Clayton, Victoria 3168, Australia

Abstract:The point-group and space-group symmetry of the controversial fluorite-based stoichiometric superlath phase of ø1 (CaZr4O9: Z=16), considered to be a coherently-intergrown subphase of lime-stabilized zirconia, is examined. Using convergent-beam and selected-area electron diffraction, it is determined that the space group of ø1 is C2/c, in apparent agreement with earlier studies utilizing other diffraction techniques.
Keywords:Fluorite  superlattice  phase  cubic  stabilized  zorconia  convergent-beam electron diffraction
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