Copper-catalyzed direct oxidation and N-arylation of benzylamines with diaryliodonium salts |
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| Authors: | Xin Liu Dan Mao ShengYing Wu JianJun Yu Gang Hong Qiao Zhao LiMin Wang |
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| Institution: | 1. Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai, 200237, China
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| Abstract: | An efficient approach for the synthesis of N-arylated amides was developed via copper(II) triflate-catalyzed direct oxidation of (aryl)methylamines to primary arylamides by air and subsequent N-arylation by diaryliodonium salts. Various substituted benzylamines could be applied in the reaction, providing a series of N-arylated amides in moderate to good yields. This method showed convenient, practical, and environment friendly advantages. |
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| Keywords: | equiv salts catalyzed Figure Methyl |
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