Equilibrium chromatographic characteristics of capillary column coated with polytrimethylpropyne for separating polar and non-polar organic compounds by gas capillary chromatography |
| |
| Authors: | Berezkin V G Popova T P Shiryaeva V E Korolev A A Malyukova I V |
| |
| Institution: | (1) Russian Academy of Sciences, A. V. Topchiev Institute of Petrochemical Synthesis, 29 Leninsky prosp., 119991 Moscow, Russian Federation |
| |
| Abstract: | The temperature dependence (50—180 °C) of the retention factor for 35 hydrocarbons and their oxygen-containing derivatives was studied using a capillary column coated with a new film-forming polymeric adsorbent polytrimethylsilylpropyne (PTMSP). The heats of adsorption for 24 organic polar and non-polar compounds on PTMSP were determined. They turned out to be lower than the heats of adsorption of the same compounds on Porapak Q widely used in gas chromatography. The new adsorbent PTMSP is characterized by high selectivity suitable for practical application. |
| |
| Keywords: | capillary gas adsorption chromatography organic polymer adsorbents polytrimethylsilylpropyne (PTMSP) sorption heat |
| 本文献已被 SpringerLink 等数据库收录！ |
