The direct formation of ketones by reaction of methyl- and aryl-(carbonyl)(iodo)pentamethylcyclopentadienylrhodium complexes with organic iodides |
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Authors: | Francesco P Fanizzi Glenn J Sunley Peter M Maitlis |
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Institution: | Department of Chemistry, The University, Sheffield S3 7HF Great Britain |
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Abstract: | C5Me5Rh(aryl)(CO)I] reacts with methyl iodide to give (C5Me5RhI2)2] and arylCOMe; similar reactions occur between C5Me5Rh(Me)(CO)I] and RI to give the ketones RCOMe (R = Ph, Me, Et, or Pr). |
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