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The direct formation of ketones by reaction of methyl- and aryl-(carbonyl)(iodo)pentamethylcyclopentadienylrhodium complexes with organic iodides
Authors:Francesco P Fanizzi  Glenn J Sunley  Peter M Maitlis
Institution:

Department of Chemistry, The University, Sheffield S3 7HF Great Britain

Abstract:C5Me5Rh(aryl)(CO)I] reacts with methyl iodide to give (C5Me5RhI2)2] and arylCOMe; similar reactions occur between C5Me5Rh(Me)(CO)I] and RI to give the ketones RCOMe (R = Ph, Me, Et, or Pr).
Keywords:
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