Catalytic enantioselective Michael addition of 1,3-dicarbonyl compounds to nitroalkenes catalyzed by well-defined chiral ru amido complexes |
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| Authors: | Watanabe Masahito Ikagawa Ayako Wang Hui Murata Kunihiko Ikariya Takao |
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| Institution: | Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology and Frontier Collaborative Research Center, O-okayama, Meguro-ku, Tokyo 152-8552, Japan. |
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| Abstract: | Well-defined chiral Ru amido complexes promoted asymmetric Michael addition of 1,3-dicarbonyl compounds including malonates, beta-keto esters, and 1,3-diketones to nitroalkenes to give the corresponding adducts with excellent ees and in excellent yields. |
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