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Zeolite analysis: PIXE,XRF or neutron activation
Authors:A. E. Pillay  M. Peisach
Affiliation:(1) Department of Chemistry, University of the Witwatersrand, P.O., 2050 WITS, South Africa;(2) National Accelerator Centre, P.O. Box 72, 7131 Faure, South Africa
Abstract:The determination of aluminium-to-silicon ratios in zeolites is of great benefit to catalyst technology and of general interest to mineralogists. However, such determinations tend to be open to error because of interferences that are due mainly to the juxtaposition of these elements in the Periodic Table. The capabilities of neutron activation, both with isotopic sources and accelerator based, of PIXE and of XRF were evaluated to establish which of these instrumental methods was best suited especially for routine on-line usage.
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