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Additivity of the entropy and definition of the temperature for quantum systems
Authors:H Roos
Institution:(1) Institute for Theoretical Physics, Groningen, The Netherlands
Abstract:A closed quantum systemL is considered which is described by a microcanonical ensemble.L consists of two rather weakly interacting subsystemsL 1,L 2. In a rigorous way, the additivity of the entropy is proved by deriving an expression for the entropy density ofL in terms of the entropy densities ofL 1 andL 2. ldquoRigorousrdquo implies that the thermodynamic limit is taken. In the second part, it is shown how a microcanonical state 
$$\omega _\varepsilon  (\Lambda ) = \mathop {\lim }\limits_{\Lambda  \to \infty } \frac{{Tr\delta ^\Delta  (H(\Lambda ) - E)A}}{{Tr\delta ^\Delta  (H(\Lambda ) - E)}}$$
of the composite system — provided this limit exists — gives rise to a ldquocanonicalrdquo stateohgr beta, when restricted toL 1, providedL 1 is very ldquosmallrdquo as compared toL 2;ohgr beta is defined as a limit of Gibbs states. This yields a definition of the equilibrium temperature beta–1.On leave of absence from the Institut für Theoretische Physik, Universität Göttingen.
Keywords:
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