One-pot regioselective synthesis and X-ray crystal structure of a stable [60]fullerene trisadduct with the e(edge),e(face),trans-1 addition pattern |
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| Authors: | Riala Maria Markoulides Marios S Moushi Eleni E Chronakis Nikos |
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| Affiliation: | Department of Chemistry, University of Cyprus, P. O. Box 20537, 1678 Nicosia, Cyprus. |
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| Abstract: | The Bingel functionalisation of C(60) with a structurally novel tether equipped with three reactive malonate groups afforded a C(2v)-symmetrical e(edge),e(face),trans-1 trisadduct in a complete regioselective manner and in an excellent yield of 65%. The [60]fullerene trisadduct showed pronounced ability to crystallise and gave X-ray quality single crystals for analysis. |
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