Novel rearrangements of 4-silyl-3-buten-2-ones |
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Authors: | Jung Michael E Piizzi Grazia |
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Institution: | Department of Chemistry and Biochemistry, University of California-Los Angeles, 405 Hilgard Avenue, Los Angeles, CA 90095-1569, USA. jung@chem.ucla.edu |
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Abstract: | Two 4-silyl-3-buten-2-ones, 2a and 2c, underwent an interesting rearrangement involving migration of the allyl or phenyl group on the silicon atom to the adjacent enone carbon when treated with various bases. |
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