| Ground State Spins of Bicarbcnes and Binitrenes,Coupled through Electron-Rich Rings |
| |
| 引用本文： | Hai Quan HU, Yong Jun LIU, Da Cheng FENG, Cheng Bu LIU(Institute of Theoretical Chemistry,Shandong University,Jinan 250010). Ground State Spins of Bicarbcnes and Binitrenes,Coupled through Electron-Rich Rings[J]. 中国化学快报, 1999, 0(11) |
| |
| 作者姓名： | Hai Quan HU Yong Jun LIU Da Cheng FENG Cheng Bu LIU(Institute of Theoretical Chemistry Shandong University Jinan 250010) |
| |
| 作者单位： | Institute of Theoretical Chemistry，Shandong University，Jinan 250010 |
| |
| 摘 要： | Therationaldesignandsynthesisofmagneticorganicmolecularmaterialshasreceivedmuchattentioninthepastfewyears'-'.Onestrategybeingcurrentlypursued'isshownschematicallyinFigurela.Ahigh-spinmoleculecanbedividedintotwocomponentsfthespin-containingfragment(SC)andtheferromagneticcouplingunit(FC).TheSCissimplyanystructurethatprovidestheunpairedelectrons,andtheFCisageneralstructuralunitthatferromagneticallycouplesanytwoormoreSCs.Ashasbeenstressedpreviously',thekeyelementinthedesignofneworganicmagneti…
|
Ground State Spins of Bicarbcnes and Binitrenes, Coupled through Electron-Rich Rings |
| |
| Hai Quan HU, Yong Jun LIU, Da Cheng FENG, Cheng Bu LIU. Ground State Spins of Bicarbcnes and Binitrenes, Coupled through Electron-Rich Rings[J]. Chinese Chemical Letters, 1999, 0(11) |
| |
| Authors: | Hai Quan HU Yong Jun LIU Da Cheng FENG Cheng Bu LIU |
| |
| Abstract: | The ground state spins coupled through electron-rich rings of bicarbenes and binitreneshave been studied at UHF/6-31G* level. The results demonstrate that ferromagnetic couplingexists in these molecules, and electron-rich rings are the potential ferromagnetic coupling units. |
| |
| Keywords: | Electron-rich ring ferromagnetic coupling bicarbene binitrene. |
| 本文献已被 CNKI 等数据库收录！ |
