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Substitution effects enhancing the lasing ability of organic compounds
Authors:Laurent Ducasse  Jean-Claude Rayez  Claude Rullière
Institution:Laboratoire de Chimie Physique A, Université de Bordeaux I, 33405 Talence Cedex, France
Abstract:Simple calculations can help to predict which derivatives in a series of organic compounds are potential lasing material. In conjugated systems, a necessary condition for lasing is that there is not less than a specific minimum energy difference between a first excited allowed and a second excited forbidden transition. This order of transition and energy spacing can be obtained by judicious substitutions even in molecules that do not meet these conditions. Lasing action in the near UV has been observed in five new compounds.
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