The acetyl radical studied by flash photolysis and kinetic spectroscopy |
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| Authors: | Hiroyuki Adachi N. Basco D.G.L. James |
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| Affiliation: | Department of Chemistry, The University of British Columbia, Vancouver, British Columbia, Canada V6T 1W5 |
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| Abstract: | The acetyl radical absorption spectrum is a broad band with maximum decadic extinction coefficient of (1.0 ± 0.1) × 104 ? mole?1 cm?1 at 215 nm and an oscillator strength of 0.23 ± 0.03. Absolute rate constants were estimated as 4.5 × 1010 ? mole?1 s?1 for the mutual interaction of acetyl radicals, and as 7.5 × 1010 ? mole?1 s?1 for the cross interaction of acetyl and methyl radicals. |
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