13C NMR studies of molecular relaxation processes in polar fluids |
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| Authors: | R. Ling G.A. Kenney-Wallace W.F. Reynolds |
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| Affiliation: | Chemistry Department, University of Toronto, Toronto, Canada M5S 1A1 |
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| Abstract: | A study of the dynamical molecular structure of a dilute polar fluid is reported, in which 13C spin-lattice relaxation times of decanol in deuterated cyclohexane are presented for the individual carbon atoms, and the results are discussed in the context of viscosity data of decanol in alkane systems. The two techniques provide complementary information about the mobility of the alcohol chains and the onset of multimer formation, which is also pertinent to the dynamics of electron solvation in the same systems. |
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