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Model of packing of cellulose acetomyristinate in Langmuir-Blodgett films |
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| Authors: | A K Khripunov Yu G Baklagina N D Stepina L G Yanusova L A Feigin V M Denisov A Ya Volkov V K Lavrent’ev |
| Institution: | (1) Institute of Macromolecular Compounds, Russian Academy of Sciences, St.-Petersburg, Bol’shoi pr. 31, St.-Petersburg, 199004, Russia;(2) Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 117333, Russia |
| Abstract: | The variation of the structural characteristics in the transition from a block polymer to a Langmuir-Blodgett film has been investigated for cellulose acetomyristinate by the methods of X-ray diffraction analysis. The effect of length and number of acid residues on the diffraction pattern of block cellulose acetomyristinate is studied. The role of acyl substituent in the formation of an ordered structure of multilayer Langmuir-Blodgett films is established. A model of packing of cellulose acetomyristinate molecules in the Y-type films is suggested. The model is based on a two-domain structure in which close-packed myristic-acid residues are located either normally or at a certain angle to the plane of glucoside rings on one side of the polymer chain. |
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