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N—(2—氯乙基)—芳香醛亚胺的合成及其与醇钠的反应
引用本文:姚子鹏,张沪秋.N—(2—氯乙基)—芳香醛亚胺的合成及其与醇钠的反应[J].复旦学报(自然科学版),1989,28(1):34-38.
作者姓名:姚子鹏  张沪秋
作者单位:复旦大学化学系 (姚子鹏,张沪秋,董庭威),复旦大学化学系(严德官)
摘    要:

关 键 词:  伯胺  亚胺  芳香醛亚胺  反应

SYNTHESIS OF N-(2-CHLOROETHYL)-AROMATIC ALDIMINES AND THEIR REACTION WITH SODIUM ALKOXIDES
Yao Zipeng,Zhang Huqiu,Dong Tingwei,Yan Deguan,.SYNTHESIS OF N-(2-CHLOROETHYL)-AROMATIC ALDIMINES AND THEIR REACTION WITH SODIUM ALKOXIDES[J].Journal of Fudan University(Natural Science),1989,28(1):34-38.
Authors:Yao Zipeng  Zhang Huqiu  Dong Tingwei  Yan Deguan  
Institution:Department of Chemistry
Abstract:N-(2-chloroethyl)-aromatic aldimines were synthesized by condensation of2-chloroethylamine and aromatic aldehydes in the presence of triethylamine andanhydrous magnesium sulphate. Unusual products N-(1-alkoxylethyl)-aldimineswere obtained in the reaction of the N-(2-chloroethyl)-aldimines with sodiumalkoxide in alcohol and the mechanism of the reaction was discussed.
Keywords:aldehydes  primary amine  imine  condensation reaction  elimination reaction  addition reaction    
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