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Double pulse laser induced breakdown spectroscopy: Experimental study of lead emission intensity dependence on the wavelengths and sample matrix
Authors:V. Piscitelli S,M.A. Martí  nez L.,A.J. Ferná  ndez C.,J.J. Gonzá  lez,X.L. Mao,R.E. Russo
Affiliation:1. Laboratorio de Espectroscopia Láser, Escuela de Química, Facultad de Ciencias, Universidad Central de Venezuela, Caracas, DC 1020, Venezuela;2. Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA
Abstract:Lead (Pb) emission intensity (atomic line 405.78 nm) dependence on the sample matrix (metal alloy) was studied by means of collinear double pulse (DP)-laser induced breakdown spectroscopy (LIBS). The measurement of the emission intensity produced by three different wavelength combinations (i.e. I:532 nm–II:1064 nm, I:532 nm–II:532 nm, and I:532 nm–II:355 nm) from three series of standard reference materials showed that the lead atomic line 405.78 nm emission intensity was dependent on the sample matrix for all the combination of wavelengths, however reduced dependency was found for the wavelength combination I:532 nm–II:355 nm.
Keywords:Double pulse LIBS   Lead   Laser induced breakdown spectroscopy
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