Total synthesis of unsaturated imine venom alkaloids of Costa Rican ant by way of Schmidt reaction via allyl/pentadienyl cations |
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Authors: | Huan Zhang Kyohei HayashiHiroki Tanimoto Tsumoru MorimotoYasuhiro Nishiyama Kiyomi Kakiuchi |
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Affiliation: | Graduate Schlool of Materials Science, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama-cho, Ikoma, Nara 6300192, Japan |
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Abstract: | Total synthesis of α,β-, and α,β,γ,δ-unsaturated imine ant venom alkaloids is described. The labile two conjugated imine alkaloids were synthesized by late stage intramolecular Schmidt reaction via allyl and pentadienyl cation intermediates. |
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Keywords: | Total synthesis Alkaloid Organic azides Unsaturated imines Schmidt reaction |
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