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Water inclusion as a trigger for modulation of anthracene arrangement and fluorescence emission of organic salt |
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| Authors: | Misa Sugino Keisuke Hatanaka Tetsuya Miyano Ichiro Hisaki Mikiji Miyata Aya Sakon Hidehiro Uekusa Norimitsu Tohnai |
| Institution: | 1. Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan;2. Department of Chemistry and Materials Science, Tokyo Institute of Technology, Ookayama 2-12-1, Meguro-ku, Tokyo 152-8551, Japan;3. Japan Science and Technology Agency (JST), PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan |
| Abstract: | An organic salt composed 9,10-bis(4-aminophenyl)anthracene and hypophosphorous acid emits yellow-green fluorescence in the crystalline state. The salt also gives water inclusion crystal which provides blue-green fluorescence. Single X-ray crystal studies revealed that water molecules induced the fluorescence change resulting from reaggregation of molecular packing. |
| Keywords: | Organic salt Inclusion crystal Fluorescence Anthracene |
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