Synthesis,characterization, and initial reaction study of two new bicyclic hypervalent iodine(III) reagents |
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| Authors: | Wen-Chao Gao Chi Zhang |
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| Institution: | The State Key Laboratory of Elemento-Organic Chemistry, The Research Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, PR China |
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| Abstract: | The synthesis of two new bicyclic hypervalent iodine(III) reagents 5 and 6 is described along with their corresponding X-ray crystal structures for the first time. A detailed comparison in the bond lengths and bond angles of reported bicyclic hypervalent iodine(III) reagents is also presented. Furthermore, an initial study shows that these two hypervalent iodine(III) reagents could promote the dipeptide coupling reaction. |
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| Keywords: | Hypervalent iodine reagent Bicyclic iodinane X-ray diffraction Structural comparison |
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