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ipso-Nitrosation of arylboronic acids with chlorotrimethylsilane and sodium nitrite |
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| Authors: | G.K. Surya Prakash Laxman Gurung Philipp Christoph SchmidFang Wang Tisa Elizabeth ThomasChiradeep Panja Thomas MathewGeorge A. Olah |
| Affiliation: | Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA 90089-1661, USA |
| Abstract: | Nitroso compounds are versatile reagents in synthetic organic chemistry. Herein, we disclose a feasible protocol for the ipso-nitrosation of aryl boronic acids using chlorotrimethylsilane–sodium nitrite unison as nitrosation reagent system. |
| Keywords: | ipso-Nitrosation Boronic acids Chlorotrimethylsilane Nitrosoarenes Regioselectivity |
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