Direct asymmetric aldol condensation catalyzed by aziridine semicarbazide zinc(II) complexes |
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Authors: | Adam M. Pieczonka Stanisław LeśniakMichał Rachwalski |
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Affiliation: | University of ?ód?, Department of Organic and Applied Chemistry, Tamka 12, PL-91-403 ?ód?, Poland |
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Abstract: | Previously obtained semicarbazides derived from N-triphenylmethyl-aziridine-2-carbohydrazide were explored as ligands in Zn(II) catalyzed diastereo- and enantioselective direct aldol reactions. Complexes of aziridine-semicarbazides with Zn(II) were efficient catalysts in reactions of acetone and hydroxyacetone with NO2-substituted aromatic aldehydes in the presence of water. |
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Keywords: | Asymmetric synthesis Chiral ligands Aldol condensation Aziridines |
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